First iron-catalyzed synthesis of oximes from styrenes.
نویسندگان
چکیده
Aryl-substituted olefins react with t-butyl nitrite and sodium borohydride in the presence of iron(ii)phthalocyanine to give oximes in moderate to high yields.
منابع مشابه
Iron catalysed nitrosation of olefins to oximes.
Fe(BF4)2·6H2O/2,6-pyridinedicarboxylic acid catalysed nitrosation of a wide variety of substituted styrenes has been developed in the presence of t-BuONO/NaBH4 under H2 pressure (10 bar) in MeOH-H2O (5 : 1) to afford corresponding oximes in good to excellent yields.
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ورودعنوان ژورنال:
- Chemical communications
دوره 15 شماره
صفحات -
تاریخ انتشار 2009